Nope. Liz Allen ignored him consistently until issue #12, (I think I'm recalling that right--the "Unmasked by Dr. Octopus" one). I was buying the comics then. I remember. Gwen Stacy, when first introduced, was KIND of interested in him, but then thought he was a stuck-up snob, and laughed at HIM...which led to Peter's thought balloon, "Why am I always so interested in women who can't see me for DUST?"