Yeah, that's it! I was trying to place just what feeling it was giving me, but couldn't quite get it. Silly artist, real people's mouths aren't usually wider than the distance between their pupils. And who's that walking away on the red carpet? It can't be Mary Jane, that person has a totally different profile!
I do have to say, that close-up of her and the coffee is really stunning. Best image of her in this whole set of scans.