Well, keeping in mind that Vicki Vale went all atwitter at the very THOUGHT of dating Bruce Wayne, and throughout her date with him kept slipping into the proverbial 'pinch me, I must be dreaming' state of mind, one may safely assume that he's considered quite a catch. And actually, I can see the ASBAR Wayne being quite the lady's man, in that 'gimme some sugar, baby' macho-man sort of way. And as for the 'haven't kissed a smoker in WEEKS' thing, come on. This is Frank Miller we're talking about here; he hasn't progressed past his Sin City stage since... well, since he started writing Sin City. And damn near EVERYONE in Sin City smokes, so I can see how Miller's Gotham would be the same - and if ASBAR Wayne IS the lady's man that Vicki seems to think he is, then I'm not surprised he can tell the brand of smokes a lady prefers just by a french kiss - he'd have plenty of opportunity to gain such expertise.