The first prority was to free the hostages. So naturally Spidey went after them first. He leaped around inside and webbed the hostage guards against the wall. Then cleared a path for the civilians to escape by through a wall. He waved them all out then cleared the rest of the building before webbing slinging his way back out.
As soon as he spotted one of Cassie’s tree trunk size legs, he jumped on and crawled up to her shoulder. He perched there and turned to glance at his girl. Hopefully she didn't knock him off again. Last time had been a close call. “Inside is clear. Wow. I feel like a parrot up here. Polly wanna hot pocket.”