There is a great chance for a Jedi/Sith line in the current canon in the Legacy of the Force books. Though, I have not read the latest one.
The Jedi/Sith line works well in the TPM era too with OCs or nearly OCs.
I mostly do femme but would do a het line if the pairing was right. I do like them to get smutty but I like plot and development as well. Would you be looking for long term or just a one or two thread deal?