Shay Mitchell - as a young Professor and/or Trophy Wife (maybe a former student of a Professor and marries up). Futa, very kinky, compulsive adulteress.
Vanessa Morgan - she's from the wrong side of the tracks / works at a strip club, but has been able to get the money to go to University to make her life better. Undecided on femme or futa.
Dove Cameron - Virgin sorority pledge and a dance student. Kind of wants to keep her virginity but wants to explore sex. She's femme. Maybe a futa virgin roommate and / or girlfriend for her? And a Mistress for an SM relationship with chastity play.