It might be awkward at first because Vi is very used to other people talking around her, so someone that didn't, she be like "buawha?"
But I can see the intimidation, given she's Captain Vi and I Have A Ship and Daggers and Sword and I Have To Yell A Lot. But she's also a really small slip of a thing, so that at least be amusing XD
They would definitely be intrigued by each other if they got over the whole "You talk." "No you talk!" thing.