She already knows that he pulled her out without her soul, but she's not blaming him for it. Actually, the other Cas has been talking about how he's been injured and whatever and he's not telling her what happened, but she's currently assuming it's because he got hurt trying to get all of her out. Regardless-- she'll forgive him, just like on the show. And she'll try to help him figure out the being human thing. She's got your back, bro. *manly shoulder pat*