Sorry it took me forever to respond to this. NaNoWriMo ate me up! I'm Grue, I've got a lot of characters, and some of them Daphne might enjoy bumping into! I've got three lycans that could immediately strike your fancy:
Shiloh is a were-dingo who works at the Lycan's Children Home, and she's a very friendly young lady who likes making new friends. She's a bit naive, but her girlfriend Jo is working on that. :V
Harvey Killian is a semi-celebrity gladiator (and a wolf). He was badly injured the other month, and then found out he was a dad, and his current arrangement with his baby momma has them taking turns watching said baby. He likes to use his daughter as chick bait, and he'd probably be a terrible flirt, but Harvey is a pretty sincere and friendly guy.
Cheyenne is the current Alpha of the Ryder clan, a group of wolf Striders that live outside of town. She's in town a lot these days because Skyler knocked her up during a display of dominance, so there's a good chance Daphne might bump into her. Cheyenne is not especially friendly or pleasant, so if you want a Frenemy of some kind, that can be arranged!