The difference is that when Spidey smacks Electro, Dr. Octopus or even Juggernaut he's doing so to protect others. Others that wouldn't have any chance if they tried to face said criminals. So he potentially saves lives there that otherwise would be lost.
Here, Spidey does something for mere self gratification. And that's fine and dandy, you know? But in the process he causes discomfort and trouble to others. Others that have no way of prevent being gipped by Spiery and the Black Cat just because they were horny.