Klaus Hargreeves, cantsmokeeggs is from The Umbrella Academy. He's a medium... at least when he doesn't do drugs or alcohol. Did I mention he's gay and saw his boyfriend die in his arms not to long ago...
Melisandre, darknfuloterror is from Game of Thrones. She's from 7x03. She is a red priestess working for the Lord of Light. She'll have her own healing store/temple called Divine Interventions.