Re: SUNSET RIDE
Pike definitely would have been doing the captain thing, making sure everyone was okay and comfortable on their horses. He's quietly impressed with Bucky's riding skills even before the snake incident.
There would have been an eyebrow of appreciation at the snake incident and a little bit of "wtf did they do this man that he has such a high threat response?"
He might make a joke that if Bucky needs a new career, trick riding is clearly an option.