Really? Awesome. Thor is one of my favs as well XD
Sam would definitely want to talk to him especially given the fact Bucky now has his memories back and if Steve is willing to go to bat for him then Sam would want to help if he can. Especially as he is all too familiar with PTSD and has as we know counselled folk in the past in regards to coming to terms with the past and everything associated with it. Plus it'll be good for Sam to get a read on Bucky, to determine he can definitely be trusted ;) totally down for exploring all of that. I imagine Sam and Thor can have some fun in regards to going out and about.
Pietro has literally held his hands up " I did not mess with your mind, I just hit you" them grinned a little lol. Incorrigible boy that he is. And that's really good to hear as I'd love to scene Pietro and Thor.