Diana Prince & Bucky Barnes
When he reaches that gloved hand out she gives his hand a firm shake, probably far stronger than a normal woman would have. It was a bit suspicious that he was still wearing his leather jacket and gloves but she wasn't one to judge another. After all, she's been to No Man's Land and around some of Steve Trevor's more interesting friends.
"Do you prefer James or Bucky?" She asks before giving a nod," Go ahead and have a seat, relax a bit."