I now bring you one Oliver Queen aka Green Arrow from Smallville. Unlike my other character here (Anna), he's probably going to be pretty friendly with everyone. He's not reserved the way she is. In addition to being a vigilante superhero (although he's completely human, unlike all of his super-powered hero friends at home), Oliver is a billionaire. His parents founded a company called Queen Industries before he was born, which he inherited when they died when he was nine. He obviously couldn't run said company until he was much older.
When he graduated from Excelsior (a private boys school), he set sail on a trip that was to be his last big hurrah before taking over at QI. Unfortunately for Oliver, his shipmates were killed by pirates and he was left for dead sans boat. He washed up on a deserted island where he was stranded for two years. During that time he made the decision that if he ever got to return home, he'd make changes and make his parents proud. For survival purposes, he fell back on a skill set that he learned from his father: archery. He made himself a bow and arrows so he wouldn't starve.
After his eventual rescue, Oliver made good on his vow: he became Green Arrow and took to the streets of Star City nightly, rescuing people who were in trouble from criminals and helping put said criminals behind bars. Of course, no one knows he's billionaire Oliver Queen, either, except for a precious few: Lois Lane, Chloe Sullivan, Clark Kent, Bart Allen, Arthur Curry, Dinah Lance and Victor Stone. The latter four are super-powered people he helped in various ways and convinced them to form a team to help "save the world" from people like Lex Luthor. They are occasionally aided by techno wiz, Chloe Sullivan, who does the "sidekick sidejob" for Oliver when he needs her help.
I've pulled him from post his ONE appearance in Smallville's seventh season, "Siren," for those familiar with the show. So he's just met Dinah, and been shot down by Lois, who just learned of his secret life as a hero.
He's open for plots and interactions! Oh and if your pups are familiar with comics or Smallville, feel free to canon puncture him. It'll blow his mind.