LOL She might be familiar with Bucky, but more as the Winter Soldier (and Fist of Hydra) than his mention on the SHIELD memorial wall. He's got something of a reputation. They're not too far apart as far as timeline. Very noticeable metal arm and all that.
Molly is fun and very skilled with illusion magic. Quentin is.... intensely awkward. He's called the Moderately Socially Maladjusted for good reason. His anxiety is not nearly as high-functioning as Victoria's.