We already know how things will go over between Pete and Emma. That'll be one crazy bitch who WON'T be letting her pants get charmed off, thank you.
Rahne however, will probably think he was dreamy ... if it wasn't for the strange odor. Sofia will think he's dreamy BECAUSE of the cigarette smell. He's like Remy, only she can understand him.
If Bobby ever learned about Pete's SECRET AGENT stuff, he'd think he was the coolest guy in the world. Until the next coolest guy in the world shows up (sorry, Jean-Paul). I've got nothing with Sam. Although Wisdom once took over X-Force, so I don't know ... maybe one day Pete can help make Sam cool? Haha. No idea.